Product ID:P-22 BLEACH BL 22.15 PART A
MSDS Date:08/11/1988
FSC:6750
NIIN:01-313-1956
MSDS Number: BPCFY

ILFORD PHOTO CORP

33 LEWIS RD
BINGHAMPTON, NY 13905
US

Emergency Phone: 800-842-9660

Info Phone: 800-421-1100/201-265-6000

Cage: 0LT87

ILFORD IMAGING USA INC

BINGHAMTON, NY 13905 US

Telephone: 607-766-3153/ FAX 201-225-3514

Cage: 0LT87

SULFURIC ACID (SARA 302/313) (CERCLA)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 15 - 18%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3/3 STEL; 9596

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENESULFONIC ACID, SODIUM SALT

CAS: 873-55-2

Fraction By Weight: 2 - 4%

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 83-78%

OSHA PEL NOT RELEVANT

ACGIH TLV: NOT RELEVANT

LD50 LC50 Mixture:ORAL LD50(RATS) IS 155 MG/M3 (H2SO4)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE-CORROSIVE.INGESTED:CAUSES
MOUTH,THROAT,ESOPHAGUS,STOMACH BURNS,GASTRIC PERFORATION & EVEN
DEATH.INHALED:FUMES CAN CAUSE DAMAGE TO NASAL & RESPIRATORY
PASSAGES.SKIN:BURNING,CHARRING & DEEP ULCERA TION.EYES:CAUSES
SEVERE DAMAGE & EVEN BLINDNESS VERY
RAPIDLY.CHRONIC-BRONCHITIS,LARYNGEAL & PULMONARY EDEMA MAY RESULT.
Effects of Overexposure:IF INGESTED: CAUSES MOUTH, THROAT, ESOPHAGUS,
STOMACH BURNS, GASTRIC PERFORATION & EVEN DEATH. FUMES CAN CAUSE
DAMAGE TO NASAL & RESPIRATORY PASSAGES. CAN CAUSE BURNING, CHARRING
& DEEP ULCERATION OF SKIN. CAUSES SEVERE EYE DAMAGE & EVEN
BLINDNESS VERY RAPIDLY.
Medical Cond Aggravated by Exposure:SKIN IRRITATION MAY BE AGGRAVATED
IN PERSONS WITH EXISTING SKIN LESION. BREATHING OF SPRAYS (SULFURIC
ACID MISTS) MAY AGGRAVATE ACUTE OR CHRONIC ASTHMA AND OTHER CHRONIC
PULMONARY DISEASE.

First Aid:SPEED IS ESSENTIAL.START FIRST AID & GET MEDICAL CARE AT
ONCE.EYES/SKIN:FLUSH WITH WATER FOR AT LEAST 15 MINUTES.HOLD
EYELIDS OPEN.INHALED:REMOVE TO FRESH AIR.PROVIDE CPR/OXYGEN IF
NEEDED.INGESTION:DO NOT INDUCE VOMITING.IF
CONSCIOUS,DRINKMILK,MILK OF MAGNESIA,OLIVE OIL/MARGARINE IN SMALL
AMOUNTS UP TO 2 OR 3 OUNCES.NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.

Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:RELEASES CORROSIVE OR HIGHLY IRRITATING
FUMES AND SMOKE. WORK UPWIND IF POSSIBLE. ACTS AS AN OXIDIZER.

Spill Release Procedures:WEAR ACID-RESISTANT CLOTHING, BOOTS, GLOVES
AND FACE SHIELD. VENTILATE AREA. STOP FLOW OF MATERIAL.
CONTAIN/ABSORB SPILLS WITH DRY SAND, EARTH, VERMICULITE. CAREFULLY
NEUTRALIZE WITH SODA ASH, SODIUM BICARBONATE, LIME. DO NOT
DISCHARGE TO SEWER.
Neutralizing Agent:LIME OR SODA

Handling and Storage Precautions:STORAGE-STORE IN COOL,DRY PLACE IN
TIGHTLY CLOSED CONTAINER.WEAR GLOVES WHILE HANDLING.
Other Precautions:AVOID BREATHING VAPORS OR MISTS. DO NOT GET IN EYES,
ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. KEEP OUT
OF REACH OF C HILDREN.

Respiratory Protection:NON REQUIRED UNDER NORMAL CONDITIONS.IF WORKING
IN A CONFINED AREA OR MISTING IS OCCURRING, USE NIOSH-APPROVED
SUPPLIED AIR RESPIRATOR, OR AN AIR-PURIFYING RESPIRATOR FOR ACID.
Ventilation:GOOD GENERAL VENTILATION IS SUFFICIENT.
Protective Gloves:RUBBER IF SPILLED
Eye Protection:SAFETY GOGGLES IN CLEANUP OF SPILLS
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
THIS PRODUCT IS A KIT CONSISTING OF: DEVELOPER PART A AND PART B (PIN A
AND B); FIXER PART A AND B (PIN C AND D); BLEACH PART A AND B (PIN
E AND F); AND BLEACH NEUTRALIZER PART A AND B (PIN G AND H).K
EY:C1.

HCC:C1
Boiling Pt:>100.C, 212.F
Vapor Pres:AS WATER
Vapor Density:AS WATER
Spec Gravity:1.13
pH:<1
Evaporation Rate & Reference:1 (WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:YELLOW LIQUID - CHARACTERISTIC ODOR
Percent Volatiles by Volume:95

Stability Indicator/Materials to Avoid:YES
DEVELOPERS, FIXERS, SULFITES, STRONG BASES, METALS
Stability Condition to Avoid:EXTREME HEAT
Hazardous Decomposition Products:SULFUR DIOXIDE. MAY RELEASE CORROSIVE
OR HIGHLY IRRITATING FUMES AND SMOKE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.